William Hyde

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Bicarbonate

In inorganic chemistry, bicarbonate (IUPAC-recommended nomenclature: hydrogen carbonate) is an intermediate form in the deprotonation of carbonic acid. It is a polyatomic anion with the chemical formula HCO−3. Bicarbonate serves a crucial biochemical role in the physiological pH buffering system.The term "bicarbonate" was coined in 1814 by the English chemist William Hyde Wollaston. The prefix "bi" in "bicarbonate" comes from an outdated naming system and is based on the observation that there is twice as much carbonate (CO2−3) per sodium ion in sodium bicarbonate (NaHCO3) and other bicarbonates than in sodium carbonate (Na2CO3) and other carbonates. The name lives on as a trivial name. According to the Wikipedia article IUPAC nomenclature of inorganic chemistry, the prefix bi– is a deprecated way of indicating the presence of a single hydrogen ion. The recommended nomenclature today mandates explicit referencing of the presence of the single hydrogen ion: sodium hydrogen carbonate or sodium carbonate. A parallel example is sodium bisulfite (NaHSO3).